Mokete John Phele1,2, Fanyana Moses Mtunzi1,2, Joe Modise2, David Shooto2,

1Department of Chemistry, Faculty of Applied and Computer Sciences, Vaal University of Technology, Vanderbijlpark, 1911, South Africa, phelemj85@gmail.com

2Institute of Chemical and Biotechnology, Faculty of Applied and Computer Sciences, Vaal University of Technology Southern Gauteng Science and Technology Park, Sebokeng, 1983, South Africa

ORIGINAL SCIENTIFIC PAPER

ISSN 2637-2150
e-ISSN 2637-2614
UDC 612.014.46:546.562-31
DOI 10.7251/STEDZ2402010P
COBISS.RS-ID 141779201

Received: 21 October 2024.
Accepted: 11 November 2024.
Published: 29 November 2024.
http://stedj-univerzitetpim.com

Corresponding Author:
Mokete John Phele, Department of Chemistry, Faculty of Applied and Computer Sciences, Vaal University of Technology, Vanderbijlpark, 1911, South Africa, phelemj85@gmail.com

Copyright © 2024 Mokete John Phele, et al.; published by UNIVERSITY PIM. This work licensed under the Creative Commons Attribution-NonCommercial-NoDerivs 4.

Citation:
Phele, M.J., Moses Mtunzi, F., Modise, J., & Shooto, D. (2024). Adsorption vinetics and thermodynamics of ciprofloxacin from aqueous solutions by magnetic iron oxide nanoparticles modified Moringa pods. STED Journal, 6(2), 10-24.

ABSTRACT

The adsorption process of metal oxide nanoparticles has been studied as an effective means of removing organic and inorganic contaminants from water and wastewater. In this study, iron (III) oxide (Fe3O4) nanoparticles were synthesized in the presence of moringa oleifera pods (MOP) as an adsorbent for ciprofloxacin (CIP) adsorption. Moringa oleifera pod biochar with Fe3O4 particles precipitated on the surface of biochar was synthesized by co-precipitation method. The effect of various parameters such as contact time, pH, metal concentration and adsorbent dosage on the removal efficiency was determined. The maximum adsorption capacity of CIP by magnetic moringa composite (MMC) was 96.12 mg/g. The Langmuir and Freundlich isotherm equations were used to analyze the equilibrium isotherm data. The adsorption process fit well with the second-order kinetics in all cases, and the Langmuir isotherm equation fitted well with the experimental data.

Keywords: Moringa Oleifera, Iron oxide, Ciprofloxacin, Nanoparticles.